Departamento de Química     |     http://quimica.cinvestav.mx
Entrar   |   30 / 04 / 2017

Dr. Felipe de Jesús González Bravo

Dr. Felipe de Jesús González Bravo

Doctorado:
Doctor en Electroquímica, Universidad de París - Denis Diderot, Francia, 1996


Tel: 5747-3728
Fax: 57 47 33 89
fgonzale@cinvestav.mx

 

Temas de Investigación 


Mecanismos de reacción electroquímicos 

  • Reducción electroquímica de quinonas en disolventes no acuosos, mecanismos de protonación directa y autoprotonación.
  • Mecanismos de oxidación electroquímica de carboxilatos e hidroquinonas.
  • Reactividad electroquímica de compuestos organometálicos.

 Electrodos modificados

  • Modificación covalente de superficies de carbono por oxidación directa de carboxilatos.
  • Desarrollo del método de modificación covalente mediante el uso de catalizadores redox.
  • Busqueda de nuevos métodos de modificación basados en la oxidación de aniones orgánicos.

Electroquímica supramolecular 

  • Analísis de interacciones por puente de hidrógeno entre especies orgánicas electrogeneradas y donadores de puente de hidrógeno.
  • Determinación de constantes de asociación con métodos basados en potencial o corriente
     
Publicaciones
Electrochimia Acta  (2012)  en prensa.
Pablo Astudillo, Drochss P. Valencia, Miguel A. González-Fuentes, Blanca R. Díaz-Sánchez, Carlos Frontana, Felipe J. González*. Electrochemical and chemical formation of low-barrier proton transfer complex between the quinone dianion and hydroquinone.
 
Journal of Electroanalytical Chemistry 681 (2012) 121-126
Drochss P. Valencia, Felipe J. González*. Estimation of diffusion coefficients by using a linear correlation between the diffusion coefficient and molecular weigth.

Journal of Organometallic Chemistry 716 (2012) 289-293
J. Benito Pelayo-Vázquez, Felipe J. González*, Marco A. Leyva, Myriam Campos, Luis Alfonso Torres, María J. Rosales-Hoz*. A ruthenium carbonyl cluster containing a hydroquinone ligand: A layered structure with a polymetallic species. Structure and electrochemical characterization.

Journal of Physical Chemistry 116 (2012) 5542-5550
Hugo A. López-Peña, Lindsay S. Hernández-Muñoz, Bernardo A. Frontana-Uribe, Felipe J. González, Ignacio González, Carlos Frontana*, Judith Cardoso*. Tacticity influence on the electrochemical reactivity of group transfer polymerization-synthesized PTMA.

Journal of Electroanalytical Chemistry 672 (2012) 28-33
Mónica Galicia, Miguel A. González-Fuentes, Drochss P. Valencia, Felipe J. González*. The effect of substituents on the anodic oxidation of aliphatic carboxylates and the passage towards a pseudo-Kolbe reaction.
 
Journal of Electroanalytical Chemistry 670 (2012) 30-35
Miguel A. González-Fuentes, Blanca R. Díaz, Alberto Vela, Felipe J. González*. Radical grafting of carbon surfaces by oxidation of 5-nitroindole derived anions
 
Electrochimica Acta 63 (2012) 287-294
Lindsay S. Hernández-Muñoz, Miguel A. González-Fuentes, Blanca R. Díaz, Felipe J. González*. Covalent modification of carbon surfaces with ferrocene groups through a self-mediated oxidation of tetrabutylammonium salts of ferrocene-carboxylic acids
 
Electrochemistry Communications 13 (2011)701-703
Lindsay S. Hernández Muñoz, Felipe J. González*. One step grafting of carbon surfaces with ferrocene groups through the self-mediated oxidation of ferroceneacetate ions
 
Electrochemistry Communications 13 (2011) 129-132
Drochss P. Valencia, Felipe J. González*. Understanding the linear correlation between the diffusion coefficient and the molecular weight. A of model to estimate diffusion coefficients in acetonitrile solutions
 
Journal of the Brazilian Chemical Society, 22 (2011) 693-701
Magali Salas*, Javier Hernández, Zaira Domínguez, Felipe J. González, Pablo D. Astudillo, Rosa E. Navarro, Evelin Martínez, Samuel Cruz-Sánchez. Electrochemical Oxidation of Caffeic and Ferulic Acid Derivatives in Aprotic Medium
 
Journal of Electroanalytical Chemistry 650 (2010) 62-67
Lindsay S. Hernández, Rogelio J. Fragoso-Soriano, Carlos Vázquez-López, Elena Klimova, Luis A. Ortíz-Frade, Pablo D. Astudillo, Felipe J. González*. Modification of carbon surfaces with methyl groups by using ferrocene derivatives as redox catalysts of the oxidation of acetate ions
 
Electrochimica Acta 55 (2010) 8325-8335
Lindsay S. Hernández, Felipe J. González, Ignacio González, Marilia O. F. Goulart, Fabiane Caxico de Abreu, Adriana Santos Ribeiro, Regério Tavares Ribeiro, Ricardo L. Longo, Marcelo Navarro*, Carlos Frontana*. Revisiting the electrochemical formation, stability and structure of radical and biradical anionic structures in dinitrobenzenes
 
Organometallics 29 (2010) 3709-3721
Brenda A. Paz-Michel, Felipe J. González-Bravo, Lindsay S. Hernández-Muñoz, M. Angeles Paz-Sandoval*. Chemistry of butadiensulfinate salts with (Cp*RhCl2)2 and the reactivity of their derivatives with tertiary phosphines
 
Organometallics 29 (2010) 3694-3708
Brenda A. Paz-Michel, Felipe J. González-Bravo, Lindsay S. Hernández-Muñoz, Ilia A. Guzei, Ma. Angeles Paz-Sandoval*. Versatile chemistry of butadiensulfinate salts with (Cp*RuCl)4: tetrameric, allylsulfene, and ion-pair ruthenium compounds
 
Organic and Biomolecular Chemistry 7 (2009) 1896-1903
Lindsay S. Hernández, Martín Gómez, Felipe J. González, Ignacio González, Carlos Frontana*. Towards a molecular-level understanding of the reactivity differences for radical anions of juglone and plumbagine: an electrochemical and spectroelectrochemical approach
 
Arkivoc 2 (2009) 239-257
Cesar R. Solorio, Eduardo Peña-Cabrera*, Jesús García, Juana López, Felipe J. González, Alejandro Alvarez. 2-Hydroxynaphthoquinones. Synthesis, electrochemical study and biological assays of activity
 
Organic and Biomolecular Chemistry 6 (2008) 3414-3420
Dulce M. Hernández, Maria A. B. F. de Moura, Drochss P. Valencia, Felipe J. González, Ignacio González, Fabiane C. de Abreu, Eufranio N. da Silva, Vitor F. Ferreira, Antonio V. Pinto, Marilia O. F. Goulart*, Carlos Frontana*. Inner reorganization during the radical–biradical transition in a nor-b-lapachone derivative possessing two redox centers
 
Journal of Electroanalytical Chemistry 611 (2007) 96-106
Luis F. Cházaro, Laurent Thouin, Emmanuel Maisonhaute, Christian Amatore, Felipe J. González*, Angeles Paz-Sandoval. Electrochemical oxidation of half-open ruthenocene compounds. Role of acyclic ligands on acetonitrile coordination
 
Journal of Electroanalytical Chemistry 610 (2007) 137-146
Pablo D. Astudillo, Annia Galano, Felipe J. González*. Radical grafting of carbon surfaces with alkylic groups by mediated oxidation of carboxylates
 
 
Journal of Physical Chemistry A 111 (2007) 8993-9002
Jimmy A. Morales, José A. Bautista, Felipe J. González, Ignacio González, Carlos E. Frontana, Martha Aguilar*. Analysis of the substituent effect on the reactivity modulation during self-protonation processes in 2-nitrophenols
 
Organic and Biomolecular Chemistry 5 (2007) 2252-2256
Dolores Castillo, Jennifer J. Mares, Marco A. Leyva, Pablo D. Astudillo, Felipe J. González, Alberto Vela, Jorge Tiburcio*. Self-assembly of pH-controlled [2]pseudorotaxanes based on a new templating motif: Bis(benzimidazolium)ethane cations and 24-crown-8 macrocycles
 
Polish Journal of Chemistry 81 (2007) 921-930
Erika Navarro, Felipe J. González,* Pablo D. Astudillo, Maribel Vázquez-Hernández, Marcos Hernández-Rodríguez, Eusebio Juaristi*. The role of alkali and alkaline earth metal ions on the hydrolysis of 2-ferrocenyl-1,3-dioxane in acetonitrile solutions
 
Journal of Electroanalytical Chemistry 604 (2007) 57-64
Pablo D. Astudillo, Jorge Tiburcio, Felipe J. González*. The role of acids and bases on the electrochemical oxidation of hydroquinone. Hydrogen bonding interactions in acetonitrile.
 
Journal of Electroanalytical Chemistry 585 (2005) 19-27
Luis F. Cházaro, Felipe J. González*, Angeles Paz-Sandoval. Electrochemical oxidation of Cp*Ru(h5-C7H11) in acetonitrile. One-electron vs two-electron generation of cationic acetonitrile coordinated   complexes
 
Arkivoc 6 (2005) 172 - 184
Magali Salas, Barbara Gordillo*, Felipe J. González*. Interaction of the reduced species of 1,4-benzoquinone with alkylated cytosine and guanine nucleobases
 
Journal of Electroanalytical Chemistry 578 (2005) 193-202
Martín Gómez, Felipe J. González*, Ignacio González. Intra and intermolecular hydrogen bonding effects in the electrochemical reduction of a-phenolic-naphthoquinones
 
Journal of Electroanalytical Chemistry 574 (2004) 33-40
Magali Salas, Barbara Gordillo, Felipe J. González*. Current measurements as a tool to characterise the H-bonding between 1-ferrocenylmethylthymine and 9-octyladenine. A voltammetric and chronoamperometric analysis
 
Current Organic Chemistry 8  (2004) 1721-1738
Martha Aguilar, Norma A. Macías, José A. Bautista, Martín Gómez, Felipe J. González, Ignacio González. Hydrogen bond and protonation as modifying factors of the quinone reactivity.
 
Tetrahedron 60 (2004) 3605-3610
Martín A. Iglesias-Arteaga, Eusebio Juaristi, Felipe J. González*. An electrochemical interpretation of the mechanism of the chemical decarboxylation of 6-carboxyperhydropyrimidin-4-ones
 
Journal of Electroanalytical Chemistry 567 (2004) 269-276
Martín Gómez, Carlos Z. Gómez, Itzia I. Padilla, Francisco J. Martínez, Felipe J. González*. Hydrogen bonding effects on the association processes between chloranil and a series of amides
 
Arkivoc, 11 (2003) 72-88
Magali Salas, Barbara Gordillo*, Felipe J. González*. Enthalpy and entropy contributions to the equilibrium of the hydrogen bonding interaction between n-octylthymine and n-octyladenine
 
Journal of Physical Chemistry A 107 (2003) 11161-11168
Jorge Garza*, Rubicelia Vargas, Martín Gómez, Ignacio González, Felipe J. González. Theoretical and electrochemical study of the quinone-benzoic acid adduct linked by hydrogen bonds.
 
Journal of the Electrochemical Society, 150 (2003) 527-534
Martín Gómez, Felipe J. González, Ignacio González*. Effect of host and guest structures on hydrogen bonding association. Influence on stoichiometry and equilibrium constants.
 
Journal of Electroanalytical Chemistry, 543 (2003) 73-81
Magali Salas, Martín Gómez, Barbara Gordillo, Felipe J. González*. Electrochemical reduction of 1,4-benzoquinone. Interaction with alkylated adenine and thymine nucleobases.
 
Electrochemistry Communications, 5 (2003) 12-15
Martín Gómez, Ignacio González*, Felipe J. González, Rubicelia Vargas, Jorge Garza. The association of neutral systems linked by hydrogen bond interactions: A quantitative approach.
 
Electroanalysis, 15 (2003) 635-645
Martín Gómez, Felipe J. González, Ignacio González*. A model for characterization of successive hydrogen bonding interactions with electrochemically generated charged species. The quinone electroreduction in the presence of donor protons
 
Journal of the Electrochemical Society, 149 (2002) 46-50
Mónica Galicia, Felipe J. González*. Electrochemical oxidation of tetrabutylammonium salts of aliphatic carboxylic acids in acetonitrile.
 
Journal of Electroanalytical Chemistry, 498 (2001) 171-180
Claude P. Andrieux, Felipe J. González, Jean-Michel Savéant*. Homolyic and heterolytic radical cleavage in the Kolbe reaction. Electrochemical oxidation of arylmethyl carboxylate ions
 
US-Patent   6217740B1 (2001)
Felipe González, Claude P. Andrieux, Jean Pinson, Jean-Michel Savéant*. Process for electrochemically producing a carbonaceous material with a surface modified by functionalized groups, novel modified carbonaceous material and application of this material.
 
Journal of Electroanalytical Chemistry, 480 (2000) 18-25
Ma. Elena Navarro, Luis F. Cházaro, Felipe J. González*, Angeles Paz-Sandoval*. Electrochemical oxidation of Cp*Ru (h5-C6H9O) under argon and oxygen Atmospheres. Generation of [Cp*Ru(CH3CN)3]+PF6- and Cp*RuO2(h3-C6H9O) ruthenium complexes
 
Electroanalysis, 9 (1998) 638-642
Felipe J. González. Cyclic voltammetry of two analogue K-group vitamin compounds in dimethylsulfoxide
 
Recent Research Developments in Electrochemistry, 1 (1998) 85-100
Alejandro Baeza, Norma Macías, Martha Aguilar, Felipe J. González, Ignacio González
Electrochemistry in buffered organic solvents. Effect of the acidity level on the extension of total pathways of the organic molecules transformation.
 
Journal of the American Chemical Society, 119 (1997) 4292-4300
Claude P. Andrieux, Felipe González, Jean-Michel Savéant*. Derivatization of carbon surfaces by anodic oxidation of arylacetates. Electrochemical manipulation of the grafted films
 
Journal of Electroanalytical Chemistry, 310 (1991) 293-303
Felipe J. González, René Miranda, Juan M. Aceves, Ignacio González*. The electrochemical reduction of perezone in presence of benzoic acid in acetonitrile
 

Av. Instituto Politécnico Nacional 2508, Col. San Pedro Zacatenco, 
Delegación Gustavo A. Madero, México D.F. Código Postal 07360
Apartado Postal: 14-740, 07000 México, D.F. - Ver ubicación
Tel: +52 (55) 5747 3800